Structural properties of poly (Vinyl Chloride)-based polymer electrolytes
Keywords:PVC, NaI, FTIR
Solid polymer electrolyte of poly (vinyl chloride) PVC-sodium iodide (NaI) was prepared using solution casting technique. FTIR results suggested that NaI interacted with PVC. Deconvolution of FTIR spectra region were carried out to estimate the relative percentage of number of free ions at the C-Cl stretching vibration band. This result is in good agreement with the conductivity studies as well as the temperature studies.
Winie, T. and Arof, A.K. (2006). Transport properties of hexanoyl chitosan-based gel electrolyte, Ionics. 12, 149–152.
Low, S.P., Ahmad, A. and. Rahman, M.Y.A. (2010). Effect of ethylene carbonate plasticizer and TiO2 nanoparticles on 49% poly(methyl methacrylate) grafted natural rubber-based polymer electrolyte, Ionics. 16, 821–826.
Mohd Noor, S.A., Yoon, H., Forsyth, M. and MacFarlane, D.R. (2015). Gelled ionic liquid sodium ion conductors for sodium batteries, Electrochim. Acta. 169, 376–381.
Vickraman, P. and Ramamurthy, S. (2006). A study on the blending effect of PVDF in the ionic transport mechanism of plasticized PVC–LiBF4 polymer electrolyte, Mater. Lett. 60, 3431–3436.
Ramesh, S., Yin, T.S. and Liew, C. (2011). Effect of dibutyl phthalate as plasticizer on high-molecular weight poly ( vinyl chloride )-lithium tetraborate-based solid polymer electrolytes, Ionics. 17, 705–713.
Zheng, F., Li, H-T., Zheng, Y-Z., Wang, D., Yang, N-N., Ding, H-Y. and Tao, X. (2022). Trimethyl phosphate-enhanced polyvinyl carbonate polymer electrolyte with improved interfacial stability for solid-state lithium battery. Rare Metal. 41, 1889-1898.
Ramesh, S. and Ng, H.M. (2011). An investigation on PAN–PVC–LiTFSI based polymer electrolytes system, Solid State Ionics. 192, 2–5.
Sim, L.N., Majid, S.R. and Arof, A.K. (2012). FTIR studies of PEMA/PVdF-HFP blend polymer electrolyte system incorporated with LiCF3SO3 salt, Vib. Spectrosc, 58, 57–66.
Aziz, S.B. and Abidin, Z. H. Z. (2013). Electrical Conduction Mechanism in Solid Polymer Electrolytes: New Concepts to Arrhenius Equation, J. Soft Matter. 2013,1–8.
How to Cite
Copyright (c) 2022 Fadiatul Hasinah Muhammad, Tan Winie
This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.